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热喷涂技术:2020,12(2):1-10
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镍基与铜基碳化硅复合镀层制备技术发展现状
(暨南大学先进耐磨蚀及功能材料研究院)
Research Status and Fabrication of Nickel,Copper Matrix SiC Composite Coatings
(Institute of Advanced Wear & Corrosion Resistant and Functional Materials)
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中文摘要: 碳化硅 (SiC) 纳米复合镀层可以改善材料的耐磨性能, 是代硬铬电镀的理想替代技术, 本文对 SiC 复合电 镀广泛使用的 Ni 基及 Cu 基复合电沉积制备工艺在耐磨方面的应用进行了概述, 对 Ni、 Cu 单金属及其合金为主 的基质金属进行了评价和总结, 在此基础上, 重点综述了近年来 SiC 复合电沉积技术的研究进展, 包括单一 SiC 颗粒及与其他复合颗粒沉积, 对其中的规律进行了总结。 最后展望了 SiC 复合电沉积技术的发展方向。
中文关键词: 复合电沉积  SiC 复合镀层  Ni 基  Cu 基
Abstract:Research Status and Fabrication of Nickel, Copper Matrix SiC Composite Coatings prepared by oxy-acetylene flame spraying and fusing. The microstructures of the coatings were analyzed by using XRD and SEM. The hardness and electrochemical properties of the coatings were measured. The slurry erosion resistance properties and mechanisms of the two coatings in fresh water and 3.5wt.% NaCl medium were studied. The results show that in the microstructure of the Ni-based alloy sprayed and fused coating reinforced with nano-WC, nano-WC is evenly embedded in γ solid solution and Cr23C6, Cr7C3 etc., the hard phase, forming dispersion strengthening, which increases the hardness by 13%. Compared with the Ni60CuMo coating, the Ni-based alloy coating of Ni60CuMo reinforced with nano-WC possesses a lower potential and a higher corrosion current density in 3.5wt.% NaCl medium and its resistance of slurry erosion in fresh water and 3.5wt.% NaCl medium, has been enhanced about 53% and 20% higher than that of Ni60CuMo coating, respectively. The addition of nano-WC significantly improves the slurry erosion resistance of the Ni-based alloy coating, but in 3.5wt.% NaCl medium, a large number of micro-batteries are formed between WC and NiCr alloy, which accelerates the erosion-corrosive wear, and its enhanced effect on the slurry erosion resistance of theNi-based alloy sprayed and fused coating is weakened.
文章编号:     中图分类号:TG174.4    文献标志码:
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曹琳,李双健,王永喆,张鹏,王启伟.镍基与铜基碳化硅复合镀层制备技术发展现状[J].热喷涂技术,2020,12(2):1-10.

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