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热喷涂技术:2021,13(1):53-59
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低温固体氧化物燃料电池失效组织演变研究
(1.矿冶科技集团有限公司 北京市工业部件表面强化与修复工程技术研究中心 特种涂层材料与技术北京市重点实验室;2.东北大学冶金学院;3.中国地质大学材料与化学学院;4.湖北大学)
Study on the Microstructure Development After the Failureof Low-Temperature Oxide Fuel Cells
(1.BGRIMM Technology Group,Beijing Engineering Technology Research Center of Surface Strengthening and Repairing of Industry Parts, Beijing Key Laboratory of Special Coating Materials and Technology;2.School of Metallurgy, Northeastern University;3.School of Materials and Chemistry, China University of Geosciences;4.Hubei University)
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中文摘要: 低温固体氧化物燃料电池 (LT-SOFC) 因具有放电功率高、 性能优异而广受关注, 但目前此类电池的稳定性 尚待提高以满足商用需求。 本文使用 LT-SOFC 常用的材料体系 (NCAL、 SDC), 采用共压法制备了样品并进行了 放电试验。 电池失效后对其组织进行了解剖, 重点分析了失效组织演变行为, 探索了引起电池失效可能的机制。 本研究还采用等离子喷涂方法在金属支撑体上制备了电极涂层, 并应用到电池片制备中。 结果表明, 通过热喷涂 技术制备电池涂层在一定程度上能够缓解电池由于结构失效造成的性能过早衰退现象。
Abstract:Low-temperature solid oxide fuel cell (LT-SOFC) has caught a lot of attention due to its good property of high output power at low temperatures. However, the stability of such fuel cells needs to be further improved for commercial applications. In this paper, NCAL and SDC were studied which were common materials in LT-SOFC systems. The co-compressed fuel cell was tested in OVC processes. After the failure of the cell, its microstructure development was analyzed to study the possible mechanism causing the failure. Plasma spray technology was also used to make electrode coatings on porous stainless steel support, which was applied in fuel cell manufacture. The results showed that the cell with the sprayed electrode coatings performed longer output life than that by the common method with solving the structure failure problem.
文章编号:     中图分类号:TG174.4    文献标志码:
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引用文本:
原慷,张睿,黄琛,董文静.低温固体氧化物燃料电池失效组织演变研究[J].热喷涂技术,2021,13(1):53-59.
Yuan Kang,Zhang Rui,Huang Chen,Dong Wenjing.Study on the Microstructure Development After the Failureof Low-Temperature Oxide Fuel Cells[J].Thermal Spray Technology,2021,13(1):53-59.

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