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热喷涂技术:2024,16(2):20-27
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酸性盐雾腐蚀对铝硅聚苯酯可磨耗封严涂层组织结构与力学性能影响研究
李姝1, 周凯旋2, 刘振1, 王静1, 钟燕1, 朱昌洪1, 房永超3, 田浩亮3
(1.中国航发四川燃气涡轮研究院;2.哈尔滨工程大学;3.中国航发北京航空材料研究院)
Microstructure and Mechanical Properties of Alsi-PHB Sealing Coatings after Acid Salt Spray Corrosion
LI Shu1, ZHOU Kaixuan2, LIU Zheng1, WANG Jing1, ZHONG Yan1, ZHU Changhong1, FANG Yongchao3, TIAN Haoliang3
(1.AECC Sichuan Gas Turbine Establishment;2.Harbin Engineerring university;3.AECC Beijing Institution of Aeronautical Materials)
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投稿时间:2024-04-24    修订日期:2024-04-29
中文摘要: 为研究铝硅聚苯酯(AlSi-PHB)可磨耗封严涂层在海洋环境下的腐蚀行为及腐蚀对涂层性能的影响,在TC4基体上利用等离子喷涂技术制备AlSi-PHB涂层可磨耗封严涂层,利用扫描电子显微镜(SEM)、X射线衍射(XRD)等测试方法,开展192 h酸性盐雾试验、硬度试验、结合强度试验,对涂层腐蚀前后的腐蚀形貌及腐蚀机理、涂层结合强度和硬度的变化进行研究。结果表明,经酸性盐雾试验后,涂层表面结构被完全破坏,涂层内部出现了较大的横向裂纹及腐蚀区域,主要腐蚀产物为Al(OH)3。涂层内部孔隙的存在为腐蚀行为发生提供了场所,腐蚀介质Cl-通过孔隙侵入到涂层的内部,在“闭塞电池”的作用下,涂层内部发生更加剧烈的腐蚀。腐蚀前后,涂层的平均硬度从(65.2±10.7) HR15Y下降到(59.6±8.5) HR15Y,平均结合强度从(11.3±1.1) MPa下降到(1.7±0.6) MPa,对涂层服役可靠性产生了影响。
Abstract:In order to study the corrosion behavior of AlSi-PHB sealing coatings in marine environment and the effect of corrosion on coating properties, the AlSi-PHB sealing coating was prepared on TC4 matrix by plasma spraying technology. The 192 h acid salt spray test, hardness test and bond strength test were carried out. Using scanning electron microscopy (SEM), X-ray diffraction (XRD) and other testing methods to study the corrosion morphology, corrosion mechanism, coating bond strength and hardness changes before and after corrosion. The results show that after 192 h acid salt spray test, the surface structure of the coating is completely destroyed, and large transverse cracks and corrosion areas appear inside the coating, and the main corrosion product is Al(OH)3. The existence of pores inside the coating provides a place for corrosion. The corrosive medium Cl- invades into the interior of the coating through the pores, and more intense corrosion occurs in the deep layer of the coating under the action of "blocked battery". Before and after corrosion, the average hardness of the coating drops from (65.2±10.7) HR15Y to (59.6±8.5) HR15Y, and the average bonding strength drops from (11.3±1.1) MPa to (1.7±0.6) MPa, which could not meet the service requirements.
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基金项目:国家重点研发计划项目(2021YFB3702004);国家科技重大专项(2017-VII-0012-0109);国家自然科学基金资助项目(52075508,52305224)
引用文本:
李姝,周凯旋,刘振,王静,钟燕,朱昌洪,房永超,田浩亮.酸性盐雾腐蚀对铝硅聚苯酯可磨耗封严涂层组织结构与力学性能影响研究[J].热喷涂技术,2024,16(2):20-27.
LI Shu,ZHOU Kaixuan,LIU Zheng,WANG Jing,ZHONG Yan,ZHU Changhong,FANG Yongchao,TIAN Haoliang.Microstructure and Mechanical Properties of Alsi-PHB Sealing Coatings after Acid Salt Spray Corrosion[J].Thermal Spray Technology,202416(2):20-27.

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